Bookcover of Stability constants of metal complexes
Booktitle:

Stability constants of metal complexes

Evaluation of stability constants of Transition Metal complexes attached with thiosemicarbazone by pH metric method

LAP LAMBERT Academic Publishing (2014-03-14 )

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ISBN-13:

978-3-659-29046-6

ISBN-10:
3659290467
EAN:
9783659290466
Book language:
English
Blurb/Shorttext:
The work presented in the Book entitled “Stability constants of metal complexes” can be summarized as below. The practical proton-ligand and metal-ligand stability constants were determined by Calvin-Bjerrum titration technique using nitric acid and constant ionic strength was maintained with sodium nitrate. It was pointed out by Irving and Rossotti, that it is neither necessary to convert pH meter reading “B” to stoichiometric hydrogen ion concentration nor to know the stoichiometric concentration of the neutral salt added to maintain constant ionic strength. The method is valid both in water and water-dioxane medium. The nitrate ion has very slight complexing tendency and the competition between nitrate ion and the ligand under study is of minor importance. This may be studied by comparing the stabilities of complexes of series of metal ions with a given ligand. For a given ligand, irrespective of its nature, the order of stability constants of complexes of bivalent ions of the first transition series are usually in the natural orders (some times called the Irving-Williams order). Cu(II)>Ni(II)>Co(II)
Publishing house:
LAP LAMBERT Academic Publishing
Website:
https://www.lap-publishing.com/
By (author) :
Rakesh Tada, Naimish Chavda, Kiran Nakum
Number of pages:
60
Published on:
2014-03-14
Stock:
Available
Category:
Chemistry
Price:
39.90 €
Keywords:
Thiosemicarbazone, stability constant

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