Bookcover of Lithium-Ion Conductors based on MIL-121 Metal Organic Frameworks
Booktitle:

Lithium-Ion Conductors based on MIL-121 Metal Organic Frameworks

A developing Field of Solid State Electrolytes

AV Akademikerverlag (2017-12-08 )

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ISBN-13:

978-620-2-20762-1

ISBN-10:
6202207620
EAN:
9786202207621
Book language:
English
Blurb/Shorttext:
This work was aimed to investigate a new type of solid state lithium (Li) ion conductor as electrolyte for all solid-state Li-ion batteries. A metal organic framework (MOF) MIL-121 was modified in two different ways in order to become Li-ion conductive. The post synthetic modifications (PSM) were lithiation with lithium acetate (LiAc) and lithium hydroxide (LiOH) as well as esterification of the carboxylic groups of MIL-121 with methanol (MeOH), ethanol (EtOH) and isopropanol. After PSM the porous samples were soaked with different liquids like common liquid electrolytes, which leads to a decreased activation energy of Li-ion jumps in the crystal lattice meaning an increased Li-ion conductivity of the material. Esterified MIL-121 was soaked with ionic liquids containing lithium bis(trifluoromethane)sulfonimide (LiTFSI), because the introduction of Li-ions to the structure was necessary.
Publishing house:
AV Akademikerverlag
Website:
http://www.akademikerverlag.de/
By (author) :
Roman Zettl, Ilie Hanzu
Number of pages:
84
Published on:
2017-12-08
Stock:
Available
Category:
Chemical technology
Price:
35.90 €
Keywords:
Solid state electrolyte, metal organic framework, Li-ion battery, impedance spectroscopy

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