Portada del libro de Emulsion Copolymerization of 1-Olefins with Carbon Monoxide
Título del libro:

Emulsion Copolymerization of 1-Olefins with Carbon Monoxide

Using Water-Soluble Palladium(II) Complexes

VDM Verlag Dr. Müller (2010-11-03 )

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ISBN-13:

978-3-639-30589-0

ISBN-10:
3639305892
EAN:
9783639305890
Idioma del libro:
Inglés
Notas y citas / Texto breve:
Three types of palladium complexes with hydroxyalkyl, phosphonate and amine substituents attached to the phosphorus donors were employed in the emulsion copolymerization of propene/CO, butene/CO, and propene/butene/CO. Depending on the chain-length of the phosphorus attached substituents in the catalysts, four variables for the propene/CO, butene/CO, and propene/butene/CO copolymers were controlled: (i) the regioregularity; (ii) the molecular weight, and (iii) the glass transition temperature and the melting point (Tg and Tm). Stable dispersions are obtained by introduction of undecenoic acid as a third or fourth monomer into the propene/CO, butene/CO, and propene/butene/CO copolymers and no phase separation, or the formation of a coagulum within ten weeks were observed. In these latices, hydrophilic carboxylic acid moieties covalently bound to the particle surface contribute to the stabilization. Using phase-transfer agents, namely methyl-beta-cyclodextrin (W7 M 1.8) in the process of the co- and terpolymerization of hydrophobic monomers in the emulsion polymerization led to better results.
Editorial:
VDM Verlag Dr. Müller
Sitio web:
http://www.vdm-verlag.de
Por (autor):
Dr. Mahmoud Shaker Sunjuk
Número de páginas:
84
Publicado en:
2010-11-03
Stock:
Disponible
Categoría:
Arquitectura
Precio:
49.00 €
Palabras clave:
Emulsion, polyketones, Water-Soluble, Palladium complexes, Phosphonate, lattices

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